Decrease in environmental pollution by recovery of metals from the tails of the acid Moa process

Main Article Content

Osniel Reyes Padilla
Anel Hernández Garces
Anolan Díaz Fernández
Esteban Alfonso Olmos

Abstract

Caring for the environment is a task for everyone in the world today, as a result of the fact that, with existing industrialization, large companies exploit mineral resources, forgetting that it is nature that is providing them, returning contaminated material to it. The objective of this work is to reduce environmental pollution by recovering metals from the tails of the Moa acid process. In this work an experiment design was carried out that organized 11 experimental runs where different formulations of tail mixtures of the acidic Moa process with sodium carbonate were applied, where the determining variables were: Calcination temperature (300, 600 and 900 0C) , calcination time (30, 50 and 70 minutes) and sodium carbonate consumption of (8, 14 and 20 g). The response variables of this design were: Iron%, percentage of chromium, aluminum and sulfate extraction. The best results were obtained with 900 ° C, 30 minutes of calcination time and 20 g of sodium carbonate consumption, obtaining a maximum iron grade of 76.8% and extractions of 72% Chrome, 63% Aluminum and 71% sulfate. The consumption of sodium carbonate is 250 kg NaCO3 / t Tails.

Article Details

How to Cite
Reyes Padilla, O., Hernández Garces, A., Díaz Fernández, A. and Alfonso Olmos, E. (2020) “Decrease in environmental pollution by recovery of metals from the tails of the acid Moa process”, INFOMIN, 12. Available at: https://infomin.edicionescervantes.com/index.php/i/article/view/153 (Accessed: 2 July 2026).
Section
Artículos Originales

References

Adriano, D. C. 2001. Arsenic. In Trace elements in terrestrial environments, Springer: 219-261.

Armienta-Hernández, M. A., & Rodríguez-Castillo, R. 1995. "Environmental exposure to chromium compounds in the valley of León". Environmental Health Perspectives, 103 (suppl 1):47-51.

Babel S. & Dacera DDM. 2006. “Heavy metal removal from contaminated sludge for land application”. A review. Waste Management, 26: 988-1004.

Ballester, F. 2005. Contaminación atmosférica, cambio climático y salud. Revista Española de Salud Pública, 79, 159-175, DOI: 10.1590/S1135-57272005000200005

Bartlett, R. J., & Kimble, J. M. 1976. "Behavior of Chromium in Soils: II. Hexavalent Forms". Journal of Environmental Quality, 5(4):383-386.

Beattie, J. K., & Haight, G. P. 1972. Chromium (VI) oxidations of inorganic substrates. Inorganic Reaction Mechanisms, Part 2 (Progress in Inorganic Chemistry, 17: 93-145.

Cobos, O. F. H., Cataño, D. L., & Hernández, H. E. 2005. "Reducción del cromo contenido en efluentes líquidos de la industria del cuero, mediante un proceso adsorción desorción con algas marinas". Scientia et Technica, 3(29):115-120

Dermont G, Bergeron M. & Mercier G. 2008. “Soil washing for metal removal: A review of physical/chemical technologies and field applications”. Journal of Hazardous Materials, 152:1-31.

Eccles H. 1999.”Treatment of metal-contaminated wastes: why select a biological process?” Trends in Biotechnology, 17:462-465.

Eschenbacher W L, Holian A, & Campion R J. 1995. Air toxics and asthma: impacts and end points. Environmental Health Perspectives , 103(suppl 6), 209-211, DOI:10.1289/ehp.95103s6209

Garcia Peña, E. 2011. Extracción de Cobalto por lixiviación ácida de los residuals sólidos de la Tecnología Carbonato Amoniacal. Tesis en opción al título de Master en Metalurgía, Moa: Instituto Superior Minero Metalúrgico “Dr. Antonio Nuñez Jimenez”, 78p.

Gallardo-Lara F & Nogales R. 1987. “Effect of the application of town refuses compost on the soil-plant system”. A review. Biological Wastes, 19:35-62.

Gallardo Martinez, D., Cabrera Diaz, I., Bruguera Amarar, N & Madrazo Escalona, F. 2013.”Evaluación de impactos ambientales provocados por la actividad minera en la localidad de Santa Lucia, Pinar del Río”. Revista Científica Avances, Vol.5 (1),enero-marzo: 98-116, ISSN:1562-3297.

Giusquiani PL, Pagliai M, Gigliotti G, Businelli D & Benetti A. 1995. “Urban waste compost: Effects on physical, chemical and biochemical soil properties”. Journal Environmental Quality, 24:175-182.

Jong, T. & Parry DL. 2003. “Removal of sulphate and heavy metals by sulphate reducing bacteria in short-term bench scale upflow anaerobic packed bed reactor runs”. Water Research, 37: 3379-3389.

Kratochvil, D., Pimentel, P. & Volesky, B. 1998. "Removal of trivalent and hexavalent chromium by seaweed biosorbent". Environmental Science & Technology, 32(18): 2693-2698.

Krebs W, Brombacher C, Bosshard PP, Bachofen R & Brandl H. 1997. “Microbial recovery of metals from solids”. FEMS Microbiology reviews; 20: 605-617.

Mardanov, A. & Herrera, V.1969.Aplicación del método de calcination alcalina y lixiviación con agua al mineral laterítico de Moa. Reporte de Investigación, No.501. La Habana, Cuba: Centro de Investigaciones para al Industria Minero Metalúrgica (CIPIMM).

Mulligan CN, Yong RN. & Gibbs BF. 2001.”An evaluation of technologies for the heavy metal remediation of dredged sediments”. Journal of Hazardous Materials , 85:145-163.

Nriagu, JO & Azcue JM . 1990. Food contamination with arsenic in the environment. In: Simmons JON and MS, ed. Food Contamination from environmental sources: Inc. N.Y. John Wiley & Sons, 121-144p.

Pérez Morales, Mayra. 2015. Inventario de Emisiones. In Maestría de Toxicología Ambiental.

Pope, C. A. & Kanner, R. E. 1993.”Acute Effects of PM10 Pollution on Pulmonary Function of Smokers with Mild to Moderate Chronic Obstructive Pulmonary Disease. American Review of Respiratory Disease, 147(6_pt_1):1336-1340, DOI: 10.1164/ajrccm/147.6_Pt_1.1336.

Rangel Cordova, A. A., Isarain Chávez, E., & Maldonado Vega, M. 2015. "Caracterización y recuperación de sales de cromo hexavalente de un pasivo ambiental". Revista Internacional de Contaminación Ambiental, 31(4): 427-437.

Secretaría de Ambiente y desarrollo sustentable. Decreto 831/93 Anexo VI. Available:<http://www2.medioambiente.gov.ar/mlegal/residuos/dec831/dec831_anxVI.htm >, [Consulted: February 11, 2020].

Stylianou MA, Kollia D, Haralambous K-J, Inglezakis VJ, Moustakas KG. & Loizidou MZ. 2007. “Effect of acid treatment on the removal of heavy metals from sewage sludge”. Desalination, 215:73-81.

Touloumi, G., Samoli, E., &Katsouyanni, K. 1996. “Daily mortality and “winter type” air pollution in Athens, Greece--a time series analysis within the APHEA project.”Journal of Epidemiology & Community Health, 50(Suppl 1): 47-s51, DOI:10.1136/jech.50.Suppl_1.s47

Ware J H, Thibodeau L A, Speizer F E, Colome S, & Ferris B G. 1981. Assessment of the health effects of atmospheric sulfur oxides and particulate matter: evidence from observational studies. Environmental Health Perspectives , 41, 255-276, DOI:10.1289/ehp.8141255

Wong JWC, Xiang L, Gu XY & Zhou LX. 2004. “Bioleaching of heavy metals from anaerobically digested sewage sludge using FeS2 as an energy source”. Chemosphere, (55):101-107.

Wright, P. J. & Weber, J. H. 1991. "Biosorption of inorganic tin and methyltin compounds by estuarine macroalgae".Environmental Science & Technology , 25(2):287-294, DOI: 10.1021/es00014a011

Xing-Run, W., Yan-Xia, Z., Qi, W. & Jian-Min, S. 2012. "Effect and removal mechanisms of 6 different washing agents for building wastes containing chromium". The Scientific World Journal, 2012.