Mineralogical characteristics of the red waste from the Dumañuecos deposit for the development of cementitious materials
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Abstract
The objective of this work is the mineralogical characterization of the red clay waste from the Dumañuecos deposit to establish its potential in replacing Portland cement. The deposit samples were characterized chemically and mineralogically using X-ray Diffraction and Atomic Absorption Spectrometry techniques. The equivalent kaolin contents were calculated and the ignition losses were determined. Pozzolanic activity analyzes were carried out using the aluminum and silicon solubility method and the correlation of the equivalent kaolin content and compressive strength. The chemical composition of the red clay waste from the Dumañuecos deposit meets the criteria established by the Cuban standard TS 528: 2013 (NC TS 528:2013 2013), being considered as mineral additions for type N cement. According to the mineralogical composition, it was established that the red clay residues of the Dumañuecos Deposit have a high content of clay minerals of the kaolinite group represented by kaolinite and nacrite; which reflects its great potential to be used as pozzolans. The red clay residues from the Dumañuecos deposit according to the Almenares Reyes methodology are type IV clays, however the variability during the activation process is associated with the presence of Fe and Al oxides, which does not have a negative impact on its use. as pozzolans, so they are considered to have good prospects for this application.
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References
Abdelaziz, G.E., Shoukry, H, Selim, A.A. & Saif, M.S. 2023. Recent Progress in Limestone-Calcined Clay Cement ( LC3 ): A Review. Materials Science Forum, vol. 1089:165-174, DOI 10.4028/p-74p7so.
Almenares Reyes, R.S. 2017. Potencialidades de arcillas caoliníticas cubanas para la obtención de materiales cementicios suplementarios. Santa Clara, Cuba: Universidad Central "Marta Abreu de las Villas".
Almenares Reyes RS, Martirena Hernández, J.F., Leyva Rodríguez, C.A., Betancourt Rodríguez, S. & Arcial Carratalá, F. 2021. Identificación y evaluación de arcillas caoliníticas para la producción de cemento ternario LC3 y adiciones minerales activas LC2. Anales de la Academia de Ciencias de Cuba, vol. 11 (No. 3):1-9.
Alujas Diaz, A., Almenares Reyes, R.S., Hanein, T., Irassar, E.F., Juenger, M., Kanavaris, F., Maier, M., Marsh, A.T.M., Sui, T., Thienel, K.-C., Valentini, L., Wang, B., Zunino, F. & Snellings, R. 2022. Properties and occurrence of clay resources for use as supplementary cementitious materials : a paper of RILEM TC 282-CCL. Materials and Structures, vol. 2. ISSN 1871-6873. DOI 10.1617/s11527-022-01972-2. Disponible en: <https://doi.org/10.1617/s11527-022-01972-2>, [Consultado: marzo 20, 2024].
Arruda Junior, E.S., de Sales Braga, N.T. & Santos Barata, M. 2023. Life cycle assessment to produce LC3 cements with kaolinitic waste from the Amazon region, Brazil. Case Studies in Construction Materials: 0-15, DOI 10.1016/j.cscm.2022.e01729.
Ben Haha, M., Termkhajornkit, P., Ouzia, A., Uppalapati, S. & Huet, B., 2023. Cement and Concrete Research Low clinker systems - Towards a rational use of SCMs for optimal performance. Cement and Concrete Research, vol. 174 ( No. March):107312. ISSN: 0008-8846. DOI 10.1016/j.cemconres.2023.107312. Disponible en: <https://doi.org/10.1016/j.cemconres.2023.107312>, [Consultado: marzo 20, 2024].
Escobar Loret de Mola, E. 2018. "Características comunes de la mineralizaciónaurífera en las provincias de Ciego de Ávila, Camaguey y Las Tunas". Revista Cubana de Geociencias, No. 2310-0060: 3-28.
Espinosa Borges, A.E., Pérez García, L.A., Leyva Rodríguez, C.A., Cruz Ramírez, Y., Cobas Torres, R.Y., Torres la Rosa, M. & Aguirre Guillot, G. 2022. "Análisis petrográfico y mineragráfico de las rocas del yacimiento de arcillas caoliníticas Dumañuecos". Minería y Geología, vol. 38 (No. 1993 8012): 53-69.
Espinosa Borges, A.E., Pérez García, L.A., Leyva Rodríguez, C.A., Almenares Reyes, R.S. & Alujas Díaz, A. 2019. Evaluación de las arcillas caoliníticas de las escombreras del yacimiento Dumañuecos para la producción de cemento de bajo carbono. S.l.: Universidad de Moa Dr. "Antonio Núñez Jiménez."
Fernández Pérez, J. 2019. Producción de cemento LC3 en Cuba : El camino de la autarquía. Cubadebate. 24 mayo 2019. pp. 6.
Flatt, R.J., Roussel, N., Bessaies Bey, H.,Caneda Martínez, L., Palacios, M. & Zunino, F., 2023. Cement and Concrete Research From physics to chemistry of fresh blended cements. Cement and Concrete Research [en línea], vol. 172, no. May, pp. 107243. ISSN: 0008-8846, DOI 10.1016/j.cemconres.2023.107243. Disponible en: <https://doi.org/10.1016/j.cemconres.2023.107243>, [Consultado: marzo 20, 2024].
Jhatial, A.A., Nováková, I. & Gjerlow, E. 2023. A Review on Emerging Cementitious Materials, Reactivity Evaluation and Treatment Methods. Buildings, vol. 13, DOI https://doi.org/10.3390/buildings13020526.
Labrador Herrera, L.M. 2018. Utilizan en Las Tunas cemento de bajo carbono. Granma. 14 marzo 2018. pp. 3.
Maier, M., Forster, B., Beuntner, N. & Thienel, K.C. 2020. Potential of a calcined recycling kaolin from silica sand processing as supplementary cementitious material. En: S. Bishnoi (ed.), Calcined Clays for Sustainable Concrete. Singapore: Springer, 75-83p.
Oficina Nacional de Normalización. 2013. NC TS 528. Cemento hidráulico - Puzolanas- Especificaciones. La Habana, Cuba.
Papakosta, A., Kanavaris, F., Pantelidou, H. & Burr Hersey, T. 2020. Re-purposed Excavated Arisings Loop Transformation of London Clay into construction resources : Supplementary cementitious material and lightweight aggregate REAL Stage 1a : London Clay material characterisation. S.l.
Redacción Digital, 2019. Cuba abrirá primera fábrica de cemento lc3 del mundo. Granma [en línea]. 24 mayo 2019. pp. 4. Disponible en: <http://www.granma.cu/cuba/2019-05-24/cuba-abrira-primera-fabrica-de-cemento-lc3-del-mundo-24-05-2019-10-05-58>, [Consultado: mayo 27, 2019].
Scrivener, K., Ben Haha, M., Juilland, P. & Levy, C. 2023. Research needs for cementitious building materials with focus on Europe. RILEM Technical Letters [en línea], vol. 7: 220‐252. Disponible en: <https://doi.org/10.21809/rilemtechlett.2022.165>,[Consultado: abril 5, 2024].
Sgarlata, C., Formia, A., Siligardi, C., Ferrari, F. & Leonelli, C. 2022. Mine clay washing residues as a source for alkali-activated binders. Materials, vol. 15 (No.1): 1-14, ISSN: 19961944, DOI 10.3390/ma15010083.
Söyek Abay, B. & Tanaçan, L. 2023. 2nd International Conference on Innovative Academic A review on Limestone Calcined Clay Cement ( LC 3 ) as an alternative ecological binder. S.l.: s.n.
Velde, B. 1995. Origin and mineralogy of clays. Clays and the environment. S.l.: Springer-Verlag Berlin Heidelberg. ISBN 978-3-642-08195-8.
Yanguatin, H., Ramírez, J.H., Tironi, A. & Tobón, J.I. 2019. Effect of thermal treatment on pozzolanic activity of excavated waste clays. Construction and Building Materials [en línea], Vol. 211: 814-823, ISSN: 0950-0618. DOI 10.1016/j.conbuildmat.2019.03.300. Disponible en: <https://doi.org/10.1016/j.conbuildmat.2019.03.300>, [Consultado: abril 5, 2024].